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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Analytical chemistry 65 (1993), S. 393-396 
    ISSN: 1520-6882
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 91 (1989), S. 4278-4284 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The bond-orientational order in molten salt LiF, KF, and KCl systems has been studied by molecular dynamics simulation. The bond spherical harmonics have been calculated for the instantaneous local structures in computer-generated configurations of the molten salts. A new method of bond spherical harmonics calculation with equal neighbor number N has been proposed. For the standard structures with different coordination number, their quadratic invariant Ql histograms with same N have been calculated and a model with parameter of square deviation have been suggested. The Ql histograms with N=4 and N=12 for some standard structures have been given and the qualitative or semiquantitative estimations of the bond-orientational orders in those three molten salt systems have been obtained. The bond angle probability distributions have also been calculated and taken as the basis for evaluating the usefulness of the new method. The results show that the local structures in molten salt systems are somewhat similar to tetrahedron while the icosahedron structure is hardly found.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Bradford : Emerald
    Soldering & surface mount technology 17 (2005), S. 38-45 
    ISSN: 0954-0911
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Purpose - Sn-Zn based lead free solders with a melting temperature around 199°C are an attractive alternative to the conventional Sn-Pb solder and the addition of bismuth improves its wetability. Whilst lead-free soldering with Sn-8Zn-3Bi has already been used in the electronics assembly industry, it is necessary to study its low cycle fatigue properties since such data have not been reported up to now. Design/methodology/approach - In this study, displacement-controlled low cycle fatigue testing of Sn-8Zn-3Bi and Sn-37Pb solder joints was done on lap shear samples. The test amplitude was varied whilst the frequency was kept constant at 0.2?Hz and failure was defined as a 50 per cent load reduction. Finite element (FE) modelling was used for analysis and the results were compared to the experimental data. Findings - The microstructure of the Sn-8Zn-3Bi solder showed a mixed phase of small cellular-shaped and coarser needle-shaped areas. Au-Zn intermetallic compounds were observed near the interface from the SEM-EDS observation. The average lifetime for the Sn-8Zn-3Bi solder joints was 17 per cent longer compared to the Sn-37Pb solder joints. The cross section observation indicated that the fatigue cracks propagated along the interface between the solder bulk and the Au/Ni layer. The locations of maximum equivalent stress from the FE simulation were found to be at the two opposite corners of the solder joints, coinciding with the experimental observations of crack initiation. Originality/value - This is believed to be the first time, the low cycle fatigue properties of Sn-8Zn-3Bi solder have been reported.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal of Chemometrics 7 (1993), S. 243-253 
    ISSN: 0886-9383
    Keywords: Orthogonal expansion ; Mapping ; Modelling ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In this paper we discuss the orthogonal expansion of data matrices and its application to mapping and modelling. Two new methods, modified optimal discriminant plane (MODP) for mapping and order Gram-Schmidt orthogonalization (OGSO) for modelling, are proposed and examples are given.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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