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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 72 (1992), S. 1149-1153 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Amorphous C/diamond films have been prepared by rf plasma enhanced vapor deposition from a CH4/Ar gas mixture. Infrared and optical-ultraviolet absorption characteristics are reported and used to characterize the bonding and optical properties of these films. It has been found that the optical band gap is not related to the hydrogen content in the films and varies according to the dc self bias developed during deposition. The IR data show that the hydrogen in the a-C/diamond films is associated with triply bonded sp1 carbon as in acetelyne. The optical band gap of the films can be varied from 1.2–4.0 eV.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 98 (1994), S. 7767-7776 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract An experimental investigation is described in which the phenomenon of “junction growth” in model conical and spherical asperities of copper, aluminium, PTFE and nylon has been examined optically. The test asperity was first normally pressed against a smooth flat surface of soda-lime glass and the contact observed through the glass surface. In the presence of the normal load the asperity deformed plastically. When a tangential force was applied, the size of the real area of contact between the two solids, as measured in situ, was found to increase for all the asperities used. Depending upon the geometry and material of the test asperity, the increase in the size of the contact area was up to 40%. The behaviour was compared with an analytical expression for junction growth in the case of a right circular cylindrical asperity. The closest agreement between the measurements and the theory was found for the 60° conical asperities of work-hardened copper and for nylon spheres. The sliding of the asperity on the glass plate caused transfer of the material of the former to the latter. This occurred for all the asperities used. Moreover, the sliding of the metallic asperities resulted in up to ∼5 μm deep grooves on them as well as on the glass plate. These observations have also been briefly discussed.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 26 (1994), S. 1151-1166 
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In many decomposition reactions, the reaction velocity can be described as a product of two functions: a temperature dependent part K(T) and the kinetic function f(1 - α), where T designates the temperature and α the fraction of reactant that has decomposed. The physical interpretation of these functions is discussed for both solid and homogeneous systems. A method is described by which f(1 - α) and K(T) can be determined from kinetic data. The mechanism of decomposition can subsequently be identified which should be consistent with the derived kinetic parameters. The method has been applied to analyze the kinetics of the thermal decomposition of nitromethane. © 1994 John Wiley & Sons, Inc.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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