ISSN:
1572-8862
Keywords:
Nickel
;
iron
;
cyclosiloxanolate cluster
;
bimetallic cluster
Source:
Springer Online Journal Archives 1860-2000
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Abstract The heterobimetallic cyclosiloxanolate sandwich clusters Na[η6-cyclo (PhSiO2)6]2[Fe(OR)]2Ni4(μ6-Cl) (R = H, Me) (1) were prepared from Na2[(PhSiO2)6]2Na4Ni4(OH)2 in the form of solvates. The new clusters 1 were characterized by spectra (UV-VIS, IR, 1H-NMR), cyclic voltammetry. conductivity, magnetic susceptibility, and single-crystal X-ray diffraction.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1022631127705
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