ISSN:
1573-8353
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The MINDO3, MNDO, AM1, and PM3 methods have been used to optimize the geometries of (+)-(4S,5S)-4-(4-nitrophenyl)-1-aza-3,7-dioxabicyclo[3.3.0]octane and (+)-(4S,5S)-4-phenyl-1-aza-3,7-dioxabicyclo-[3.3.0]octane. It has been shown that the stereospecificity, of the reaction of the former with methyl iodide is due to the high stability of one of the possible conformers.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF02323386
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