ISSN:
1573-4889
Keywords:
BaTiO3
;
kinetics
;
solid state
Source:
Springer Online Journal Archives 1860-2000
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
Notes:
Abstract The solid-state reaction between barium carbonate and rutile powders to form barium metatitanate BaTiO3 was studied by thermogravimetric analysis, X rays, and microscopy. Phase-stability domains were drawn in a temperature— $${\text{p}}_{CO_2 } $$ , diagram. The dependence of the reaction kinetics on $${\text{p}}_{CO_2 } $$ , $${\text{p}}_{O_2 } $$ or $${\text{p}}_{N_2 } $$ is discussed. In particular, the rate continuously decreases when $${\text{p}}_{CO_2 } $$ , or $${\text{p}}_{N_2 } $$ increases, but it reaches a maximum as a function of $${\text{p}}_{O_2 } $$ .
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00715871
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