ISSN:
1600-5368
Quelle:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Thema:
Chemie und Pharmazie
,
Geologie und Paläontologie
,
Physik
Notizen:
The title compound, [Ni(C17H34N4)](ClO4)2, has singlet ground-state nickel(II) complex cations in tetrahedrally twisted square-planar coordination by the four N atoms of the 15-membered diamine diimine tetraazamacrocycle and disordered perchlorate anions, linked into molecular clusters by N—H...O hydrogen bonds and weak Ni...O interactions. The cation has approximate twofold symmetry, with bond lengths Ni—Namine of 1.920 (2) and 1.924 (2) Å, and Ni—Nimine of 1.915 (2) and 1.929 (2) Å, and trans–N—Ni—N angles of 165.1 (1) and 163.4 (1)°, with the shortest Ni...O distance being 3.27 (3) Å.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1107/S1600536800020559
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