ISSN:
0021-8995
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Schiff bases of hydroxy benzaldehydes with aliphatic and aromatic 1,2-diamines were re-sinified in HCHO in alkaline media. These resins were found to form complexes readily with Cu(II), Co(II), and Ni(II). The materials were characterized by infrared, 1H-NMR, UV-visible (UV-vis) spectral studies, and thermogravimetric analyses. The phenolic oxygen and the azomethene nitrogen were the ligating sites, one or more lattice positions in polychelates being occupied by water molecules. 1H-NMR provided evidence for bridging methylene and terminal methylol groups. The UV-vis spectra showed weak absorptions in the d - d transition range. Capacity studies of the resins indicated metal loading up to 70% at room temperature in an appropriate pH of the salt solutions. The effects of contact time, particle size of the sorbents, resin quantity, and pH on the adsorption characteristics were studied. In the pH range 3-8, the resins derived from the structurally rigid Schiff bases exhibited higher capacity for the metal ions than the resins derived from structurally flexible Schiff bases. Kinetic parameters computed from the thermogravimetric data indicated the resins to be more stable than the corresponding polychelates. © 1996 John Wiley & Sons, Inc.
Additional Material:
7 Ill.
Type of Medium:
Electronic Resource
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