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Stability and reactivity of the α-cyclodextrin complexes of 4-methylperbenzoic acid (1996)

Davies, D. Martin ; Deary, Michael E.

Chichester : Wiley-Blackwell

Journal of Physical Organic Chemistry 9 (1996), S. 433-435

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ISSN: 0894-3230

Keywords: Chemistry ; Theoretical, Physical and Computational Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: A kinetic study of the α-cyclodextrin-mediated oxidation of methyl 4-nitrophenyl sulphide by 4-methylperbenzoic acid suggests that the stability constant for the cyclodextrin-peracid complex is two orders of magnitude greater than the value determined previously. Potentiometric studies confirmed this and showed that the 4-methylperbenzoate anion forms a complex of stability similar to that of the molecular acid. A less stable 2:1 cyclodextrin-4-methylperbenzoic acid complex is also observed.

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

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