ISSN:
0538-8066
Schlagwort(e):
Chemistry
;
Physical Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
The kinetics of the reaction of MoOS2(S2CNR2)2 (R = CH3, C2H5, n-C3H7) with PPh3 have been studied using a Stopped-flow method. It was found that these MoOS2(S2CNR2)2 complexes react with PPh3 in the form of an irreversible second-order reaction. The rate constants at 25°C are respectively 48.4, 23.8, and 20.8 mol-1 dm3 s-1 and the activation energies are 4.8, 4.9, and 5.0 Kcal/mol with R = CH3, C2H5, and n-C3H7.
Zusätzliches Material:
8 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/kin.550210902
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