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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 1 (1879), S. 175-175 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 30 (1995), S. 1203-1208 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The structure of new submicronic spherical Ag-Pd powders (75/25 and 70/30 wt/wt% as spheres of mean diameter ca. 300 nm) has been investigated by various techniques. X-ray diffraction, carried out on both powder and single particles, showed two distinct metal phases, the first one being pure silver, the second one slightly alloyed palladium. X-ray microanalysis performed under SEM indicated that each grain displays intermetallic character, both metals being present in proportion close to the mean composition. Space-resolved information has been obtained by three different techniques: X-ray microanalysis carried out under transmission electron microscopy, X-ray photoelectron spectroscopy and secondary ion mass spectrometry, the three of them leading to converging results. Each grain appears as a core made of pure silver surrounded by a 10–15 nm thick layer of slightly alloyed palladium with a mean Pd/Ag ratio 89%/11% which possibly increases from inside to outside.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 30 (1995), S. 628-632 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Various properties of submicronic silver-palladium powders (70/30 and 75/25 Ag/Pd % wt/wt), recently obtained by a new process of precipitation in aqueous solution, are described. These powders are intended to be used in the multilayer ceramic capacitor industry. The morphology of the particles has been analysed through various measurements, such as SEM images, tap density, BET surface area, and the size distribution by a sedimentation technique. The powders were found to be made of spherical shaped particles of mean diameter close to 0.3 μm with a narrow size distribution. The individual grains were agglomerated only to a small extent. After being conditioned as a paste by blending with an organic binder, screen-printed and fired, the particles sintered into a conductive layer of low resistivity (15–30 μWcm for 2 μm thickness) with only a few remaining voids, as observed by SEM. Thermal measurements indicated no melting of a pure silver phase at 960 °C, thus indicating that alloying was achieved before this temperature.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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