ISSN:
1022-1352
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
2,5-Bis(alkylthio)terephthalic acids (and their acyl chlorides) were prepared by nucleophilic substitution of diethyl 2,5-dibromoterephthalate with octane-, dodecane- and hexadecanethiol. The poly(ester anhydrides) were obtained by thermal polycondensation of disubstituted terephthaloyl chlorides with silylated 4-hydroxybenzoic acid and silylated hydroquinone. The resulting polymers were characterized by elemental analyses, inherent viscosities, differential scanning calorimetry (DSC) and wide-angle X-ray scattering (WAXS) measurements, optical microscopy and 13C NMR cross polarization/magic angle spinning (CP/MAS) spectroscopy. These measurements suggest that the disubstituted poly(ester anhydrides) form a sanidic type of layer structure in the solid state. Increasing length of the alkyl substituents favours the formation of ordered paraffin domains between the stacks of the main chains. The stability of these quasicrystalline paraffin domains decreases with increasing mole fraction of the anhydride groups. In contrast to their monosubstituted analogues the disubstituted poly(ester anhydrides) do not form normal nematic melts.
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/macp.1994.021950312
Permalink