ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
A PE-spectroscopic study of exo- and endo-2-norbornyl iodides suggests that the relative ability of the 2-norbornyl group to stabilize an electron deficiency on a substituent X (e.g. I) in exo- or endo-position depends on the location of the positive charge. There is no difference if the positive hole is strongly localized on on the substituent X (e.g. the 5p-1 state of the title compounds). On the other hand, our results indicate that teh positive hole semi-localized in an exo-C—X bond is better stabilized by the 2-norbornyl group than a semi-localized, positive hole in an endo-C—X bond.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19840670704
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