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Tetrakis(dimethylamido)vanadium(IV) (2001)

Dubberley, Stuart R. ; Tyrrell, Ben R. ; Mountford, Philip

Oxford [u.a.] : International Union of Crystallography (IUCr)

Acta crystallographica 57 (2001), S. 902-904

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ISSN: 1600-5759

Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001

Topics: Chemistry and Pharmacology , Geosciences , Physics

Notes: The title compound, [V(C2H6N)4], (I), has non-crystallographic D2d molecular symmetry and contains an approximately tetrahedrally coordinated V atom with dimethylamido ligands. Each N atom features a nearly trigonal planar geometry. There are two independent molecules of (I) in the asymmetric unit. The results are compared with those previously reported for gas-phase electron-diffraction studies [Haaland, Rypdal, Volden & Andersen (1992). J. Chem. Soc. Dalton Trans. pp. 891–895].

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1107/S0108270101008368

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