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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Nutrient cycling in agroecosystems 41 (1995), S. 77-85 
    ISSN: 1573-0867
    Keywords: sequential extraction ; trace elements ; Egypt ; sewage sludge ; soils
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Three separate samples taken from particular location of El-Gabal El-Asfar soils treated with composted sludge and irrigated with liquid sludge effluent were compared with untreated soil. These soils were sampled at 5 depths, i.e. 0–15, 15–30, 30–45, 45–60 and 60–75 cm to estimate the forms of nine trace metals in the solid phase. The soils had been amended with sewage sludge and irrigated with sludge liquids for different periods, i.e. 20, 40 and 60 years. The soil samples were fractionated by sequential extraction to estimate the quantities of these metals in “exchangeable”, “sorbed” “organic”, “carbonate”, and “sulfide” forms. Data reveal that most of these elements were concentrated (preferential fixation) in the surface layer (0–15 cm), possibly because of the slight decrease in soil apparent density resulting from sludge application. The trace metal contents in exchangeable and sorbed forms of most metals were very low. Sulfide, carbonate and organic forms were shown to be the dominant fractions for most trace metals under study and varied from one element to another. Nevertheless, at least 6 of these metals have a common behaviour. At the longterm addition of sludge application, the predominant metals were: Zn, Fe, Mn, Cr, Ni and Co in sulfide form; Cu in organic form, and Pb and Cd in the carbonate form.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of radioanalytical and nuclear chemistry 109 (1987), S. 153-167 
    ISSN: 1588-2780
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Fourteen clay samples separated from calcareous, lacustrine, Nile alluvium and desert alluvium soils of Egypt were analyzed by pure instrumental neutron activation analysis. Elemental composition was determined by high resolution gamma-spectrometry on samples irradiated with reactor neutrons using the monostrandard technique. This was carried out in the nuclear research center of Karlsruhe, West Germany. As many as 17 trace elements, beside Ca, K, and Na, were quantitatively determined. The spectra of chosen activated clays are given. Data reveal that the content of the trace elements As, Cs, Hf, Sb, Sc, Sm, Yb, Th and U were found within a narrow range despite location and depths of clay samples. Nevertheless, the contents of some elements mainly Ce, Cr and La had a wide range. In brief, the presence of any elements in higher or lower levels in certain clays is contingent on the occurence of its bearing minerals, nature of parent sediments and depositional environments of these sediments.
    Type of Medium: Electronic Resource
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