ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Conclusions 1. C-H acids of a number of polynitroalkanes with ether-type solvents form intermolecular hydrogen bonds, forming stable complexes with a 1∶1 composition. 2. The replacement of the methyl group in the α-position of C-H acids by a nitro group increases their proton donor capacity and the energy of the hydrogen bond, 3. The change in the structure of the investigated ethers-hydrogen acceptors — leads to a change in the value of the dissociation constant of the complexes and does not affect the shift of the C-D band and, consequently, the energy of the hydrogen bond.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01106642
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