ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
On the Reaction of Hexafluoroacetone Azine with Phosphites and Tris(dimethylamino)phosphanePhosphites as well as tris(dimethylamino)phosphane react with hexafluoroacetone azine (1) under rearrangement to yield [5,5,5-trifluoro-2,2,4-tris(trifluoromethyl)-1,3-diaza-3-pentenylidene]phosphoranes 4. 1H n.m.r., 31P n.m.r., i.r., and mass spectra of the new compounds are described.
Notes:
Die Umsetzung von Phosphiten wie auch von Tris(dimethylamino)phosphan mit Hexafluoraceton-azin (1) führt unter Umlagerung zu [5,5,5-Trifluor-2,2,4- tris(trifluormethyl)-1,3-daiza-3-pentenyliden]phosphoranen 4. 1H-NMR, 31P-NMR-, IR- und Massenspektren der neuen Verbindungen werden beschrieben.
Additional Material:
9 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19741070513
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