ISSN:
1434-193X
Keywords:
Cyclophanes
;
EPR Spectroscopy
;
Cyclic voltammetry
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
We report a high-yield synthesis of 3,5,17,19-tetrakis(4′-alkylbenzoyl)-1,8,15,22-tetrathia[1.1.1.1]metacyclophanes 7[1] via condensation of dithioresorcinols 3 with benzoyl substituted meta-dichlorobenzenes 6. The underlying reaction mechanism is discussed. The solid-state structure of the macrocycle and the reduction properties of 7 have also been investigated.
Type of Medium:
Electronic Resource
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