ISSN:
0030-493X
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Both positive and negative plasma desorption mass spectra of the three-dimensionally non-molecular material [Cd(SC6H4-2-CH3)2]∞ contain fragment ions directly related to the lattice structure of the material. Fragment ions are observed which correspond with [CdSC7H7]+· and [CdS2C7H7]-· which do not involve proton transfer reactions. In contrast, a fragment ion [CdS2C14H13]-· would appear to involve a deprotonation reaction. The scarcity of protonated positive ion fragments may be a consequence of the sample structure and/or constraints of the analysis system.
Additional Material:
8 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/oms.1210271011
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