ISSN:
1573-8353
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The literature data on reactions involving electrophilic heterocyclization of δ, ɛ-unsaturated alcohols, 2-allylphenols, oxiranes, aldehydes, and ketones are correlated. The factors that affects the reactivities of the unsaturated compounds (the structure of the substrate, the nature of the electrophile, and the nature of the solvent) in intramolecular cyclization are discussed. The problems of the regioselectivity of the addition and the stereochemistry of the resulting cyclization products are examined, and kinetic data are presented.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00506356
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