ISSN:
1573-4803
Source:
Springer Online Journal Archives 1860-2000
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
Notes:
Abstract This paper explores the possibility of constructing modulus-mechanism maps for amorphous polymers. Four regimes are identified: the glassy regime, the visco-elastic regime, the rubbery regime and the regime of viscous flow (melting), truncated by decomposition. Constitutive laws for each regime are assembled and adapted to give a good description of a large body of experimental data for amorphous polymethylmethacrylate and polystyrene. The adjusted laws are then used to construct diagrams which relate the time and temperature-dependent modulus,E(t, T), to the temperature and the loading time (or frequency). The diagrams are divided into fields corresponding to the four regimes. A diagram summarizes the small-strain mechanical behaviour of the polymer over a wide range of conditions.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00553357
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