ISSN:
1573-9171
Keywords:
manganese, dicarbonyl(cyclopentadienyl) complex
;
alkyl and aryl thiophosphites
;
Mn-P complex, crystal structure
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Cp(CO)2Mn · THF reacts in THF with thiosters of phosphorus acid, P(SR)3, to give new complexes Cp(CO)2MnP(SR)3 in which the manganese atom is coordinated to the phosphorus atom. The X-ray crystal structure of compounds with R = Pri and Ph was established. The metal atom has a coordination enviroment of the three-legged “piano stool” type. The bond angles OC-Mn-CO and OC-Mn-P are 90.6–95.9(4)°. Bond distances are: Mn-P 2.188(2) and 2.171(2) E, P-S 2.097(3)-2.137(3) E.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01558079
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