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  • 1
    Electronic Resource
    Electronic Resource
    Complex formation of trinitromethane and 1,1-dinitroethane with etheetype solvents (1976)
    Springer
    Russian chemical bulletin 25 (1976), S. 509-511 
    Details
    ISSN: 1573-9171
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Conclusions 1. C-H acids of a number of polynitroalkanes with ether-type solvents form intermolecular hydrogen bonds, forming stable complexes with a 1∶1 composition. 2. The replacement of the methyl group in the α-position of C-H acids by a nitro group increases their proton donor capacity and the energy of the hydrogen bond, 3. The change in the structure of the investigated ethers-hydrogen acceptors — leads to a change in the value of the dissociation constant of the complexes and does not affect the shift of the C-D band and, consequently, the energy of the hydrogen bond.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01106642
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Bis(fluorodinitromethyl)mercury complexes (1972)
    Springer
    Russian chemical bulletin 21 (1972), S. 2462-2465 
    Details
    ISSN: 1573-9171
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Conclusions 1. The complexes of bis(fluorodinitromethyl)mercury (BFM) with various aprotic solvents, which are p-donors (dimethoxyethane, diglyme, dimethyl sulfoxide, sulfolane, hexamethyl triamidophosphate, dioxane), were obtained and isolated in the crystalline state. 2. BFM forms complexes that differ in the substrate: ligand ratio (1∶1 and 1∶2). 3. It was established by IR spectroscopy that a covalently constructed compound remains in all of the studied BFM complexes.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00850094
    Library Location Call Number Volume/Issue/Year Availability
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    Paper (German National Licenses)
    Fulltext
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