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Asymmetric hydrolyses of 1,2- and 1,3-diacetoxycyclohexanes with the cultured suspension cells of Marchantia polymorpha (1997)

Hirata, Toshifumi ; Izumi, Shunsuke ; Aoki, Masahiro ; [weitere]

New York, NY [u.a.] : Wiley-Blackwell

Chirality 9 (1997), S. 250-253

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ISSN: 0899-0042

Schlagwort(e): 1,2-diacetoxycyclohexanes ; 1,3-diacetoxycyclohexanes ; 2,3-diacetoxynorbornanes ; 2,7-diacetoxynorbornane ; enantioselective hydrolysis ; biocatalyst ; cultured plant cells ; Marchantia polymorpha ; Chemistry ; Organic Chemistry

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: Very high enantioselectivities were observed in the hydrolysis of racemic 1,2- and 1,3-diacetoxycyclohexanes and their derivatives by cultured cells of Marchantia polymorpha in suspension. Asymmetry was also induced in the hydrolyses of meso-1,2- and 1,3-diacetates to the corresponding monoacetates. These findings indicate that these cultured cells hydrolyze the acetoxyl groups enantioselectively at the stereogenic center of R-configuration. Chirality 9:250-253, 1997. © 1997 Wiley-Liss, Inc.

Zusätzliches Material: 2 Ill.

Materialart: Digitale Medien

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