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  • 1
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    The Hague : Periodicals Archive Online (PAO)
    The Journal of Value Inquiry. 26:1 (1992) 133 
    ISSN: 0022-5363
    Topics: Philosophy
    Description / Table of Contents: Forum
    Notes: Special Issue: Insensitivity, Egoism, and the Ethical Community
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  • 2
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    The Hague : Periodicals Archive Online (PAO)
    The Journal of Value Inquiry. 27:3/4 (1993) 527 
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  • 3
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    Aberdeen, etc. : Periodicals Archive Online (PAO)
    Scottish historical review. 1 (1903/1904) 58 
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  • 4
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    Aberdeen, etc. : Periodicals Archive Online (PAO)
    Scottish historical review. 1 (1903/1904) 113 
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Physics and chemistry of minerals 16 (1989), S. 697-703 
    ISSN: 1432-2021
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: Abstract Celadonite from the northwestern Mojave Desert area of California was examined by detailed Mössbauer spectroscopy at temperatures from 10 K to 400 K. In addition to the predominant Fe3+ doublet with isomer shift δ∼0.4 mm s−1 and quadrupole splitting Δ ∼ 0.4 mm s−1, another Fe3+ doublet with δ∼ 0.4, Δ∼1.2 mm/s and two Fe2+ doublets with δ∼1.1, Δ ∼ 1.7, 2.7 mm s−1 at 300 K were distinguished. The minor Fe3+ component is ascribed to dehydroxylated surface sites. Most of the remaining Fe(∼90%) is M2 cis-OH octahedral in an ordered M+−M2+ array. However, about 10% is M1 trans-OH Fe2+. Isomer shift vs. T gives Debye temperatures of 570 K for Fe3+ in M2 and 380 K for both Fe2+ sites, indicating greater vibrational freedom for Fe2+. Quadrupole splitting Δ vs. T for Fe2+ gives a valence electronic energy splitting of 760 cm−1 between the ground and first excited state for M2. The M1 sites have a more drastic variation in Δ vs. T which indicates not only a lower first excited state but a rhombic distortion at these sites. A proposed explanation is a neighboring M2 site vacancy. The soil clay formed from this celadonite, which is mostly Fe-rich smectite, was also studied by Mössbauer spectroscopy. About half the Fe2+ has been oxidized in the clay, but the isomer shifts and quadrupole splittings are essentially the same as in the original celadonite. A texture orientation in the clay absorber was detected by measuring the absorber at 55° to the source radiation. This texture effect produces asymmetric doublets in the usual 90° measurement.
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 1573-515X
    Keywords: biogeochemical processes ; calcium ; chaparral ; magnesium ; Mediterranean ecosystem ; weathering rate
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract Large earthen-walled lysimeters at the San Dimas Experimental Forest in southern California present a unique opportunity to assess vegetation effects on biogeochemical processes and cation release by weathering in controlled soil-vegetation systems where archived samples of soil parent material are available for comparison. The lysimeters were filled in 1937 with homogenized fine sandy loam derived on site from the weathering of diorite, and planted in 1946 with scrub oak (Quercus dumosa) and Coulter pine (Pinus coulteri). Changes in base cation contents were measured in above-ground biomass, and total and exchangeable soil pools to a depth of 1 meter. All cations in the non-exchangeable soil pool decreased relative to the initial fill material, indicating release by weathering. Sodium and K were depleted from both exchangeable and non-exchangeable pools of the soils. Plant uptake of Na was minimal, whereas K storage in vegetation exceeded the loss from the exchangeable soil pool. In both soil-vegetation systems, but especially for oak, there was an increase in exchangeable Ca and Mg. For all base cations, storage in above-ground biomass was greater for oak, whereas losses by weathering from the non-exchangeable soil pool were greater under pine. Strong evidence supports biocycling as a controlling mechanism resulting in greater Ca and Mg release by weathering under pine. In addition, decreases in non-exchangeable Ca and Mg were strongly correlated to decrease in Si under oak, whereas no correlation was observed under pine. We conclude that weathering reactions or stoichiometry differed between vegetation types.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 11 (1967), S. 1941-1950 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The dilute solution properties of hydroxyethyl starch (HES) were examined by using the techniques of osmometry, light scattering, and viscometry. The molecular weight range was approximately 2 × 106-0.06 × 106. Since HES is a branched molecule, its properties were compared with those of two linear counterparts, ethyl hydroxyethyl cellulose and hydroxyethyl cellulose. The branching index g was estimated to be about 0.3 when calculated from the intrinsic viscosity, radii of gyration, and second virial coefficients.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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