ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Conclusions 1. We have examined the radical cotelomerization of ethylene and propylene with CCl4 at 90°C with benzoyl peroxide initiation. Among the reaction products we identified two cotelomers with two monomer units, CCl3CH2CH(CH3)CH2CH2Cl, CCl3CH2CH2CH2CHClCH3, and three cotelomers with three monomer units, CCl3CH2CH(CH3)CH2CH2CH2CH2Cl, CCl3CH2CH2CHzCH2CH2CHClCH3, and CCl3CH2CH(CH3)CH2CH2CH2CHClCH3. 2. The influence of the polar factors persists throughout all stages of the cotelomerization of CCl4, with ethylene and propylene, two monomers that differ less in polar properties than the monomer pairs examined earlier.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00949631
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