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  • 1
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Differential scanning calorimetry (DSC) measurements have been carried out on a number of poly(butylene terephthalate) (PBT)/BPA polycarbonate (PC) blends prepared by melt compounding and solution casting from hexafluoroisopropanol (HFIP). The results clearly indicate that appreciable mixing of the two polymers takes place in the melt phase whereas complete separation is observed in cast films. The failure of the casting procedure to mimic the melt blending results is related in part to liquid-liquid phase separation and to crystallization of both polymers from the casting solvent.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 27 (1987), S. 1006-1014 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Brittle failures of large plastic structures observed in the field may have occurred at much higher loads than implied from the fracture surfaces, indeed, as if very ductile failures had occurred. It has been demonstrated that these brittle failures may be a direct result of high energy storage upon impact in large compliant systems. A rubber-toughened blend of polybutylene terephthalate (PBT) and polycarbonate (PC) was highlighted in this study. Soft steel springs were used in series with compact tension samples to simulate the high energy-storing capability of large compliant structures, Ductile and stable fractures of compact tension samples of the blend were observed at all of the temperatures tested down through -30°C. With the insertion of springs to simulate large compliant structures, however, unstable failures resulted. At 25°C, initial ductile crack growth was followed by ductile but unstable failure. At -30°C, initial ductile crack growth was followed by brittle unstable failure. These instabilities resulted from the excessive amount of stored energy released by the system during initial crack growth. A higher rubber variant of the PBT/PC blend as well as acrylonitrile-butadiene-styrene (ABS) and polycarbonate exhibited similar behavior.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 17 (1987), S. 496-496 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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