ISSN:
1434-1948
Keywords:
Hydridic-protic hydrogen interactions
;
Amine boranes
;
1,3,5-Heterocyclohexanes
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The molecular structures of 5-methyl-1,3-dithia-5-aziniumcyclohexane iodide, 5-chloroborane-5-methyl-1,3-dithia-5-azacyclohexane, 3,5-bis(borane)-3,5-dimethyl-1-thia-3,5-diazacyclohexane, and 1-borane-1,3,5-trimethyl-1,3,5-triazacyclohexane were determined by X-ray diffraction studies. Interactions between hydridic and protic hydrogen atoms are present when the distances between hydridic and protic hydrogen atoms are shorter than 265 pm and angles for B-N-C bonds are smaller than 107.6(3)°. These interactions explain the conformation of the borane adducts in the solid state.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
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