ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
X-Ray Structure Analysis of a Carbene Addition Product to Dicarbonyl-η5-methylcyclopentadienyltetrahydrofuranmanganese, μ-Cyclobuta[1, 2-a:3, 4-a′] dicyclopentene-bis-(dicarbonyl-η5-methylcyclopentadienylmanganese),[( η5-C5H4CH3)Mn(CO) 2]2(μ2-C10H8)The crystal and molecular structure of the title compound has been determined by means of X-ray structure analysis. The species is the first example of an oligocyclic dicarbene stabilized by complex formation.
Notes:
Die Kristall- und Molekülstruktur von μ-Cyclobuta[1,2-a:3,4-a′]dicyclopenten-bis[dicarbonyl-η5-methylcyclopentadienylmangan] (1) wurde mittels Röntgenstrukturanalyse ermittelt. 1 ist das erste Beispiel eines komplexstabilisierten oligocyclischen Dicarbens.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19804600119
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