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  • 1
    Electronic Resource
    Electronic Resource
    Structure of the species formed from molybdenum naphthenate in the reaction with 1-phenylethyl hydroperoxide (1989)
    Springer
    Reaction kinetics and catalysis letters 38 (1989), S. 115-118 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract Данные ИК-спектроскопии и элементарного анализа свидетельствуют о том, что заглавное соединение, вероятно, имеет структуру MoOL2ORH или MoOL2OORH. Эти соединения образуются непосредственно из радикала в координационной сфере катализатора (L=лиганд).
    Notes: Abstract IR and elemental analysis data indicate that the probable structure of the title compound is MoOL2ORH or MoOL2OORH which is formed directly from the radical within the coordination sphere of the catalyst (L=ligand).
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02126262
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    On the mechanism of propylene epoxidation catalyzed by molybdenum naphthenate (1979)
    Springer
    Reaction kinetics and catalysis letters 12 (1979), S. 57-62 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract Изучена кинетика каталитического эпоксидирования пропилена гидроперекисью этилбензола. Сама реакция эпоксидирования — это молекулярное взаимодействие между пропиленом и комплексом катализатора с гидроперекисью. Ряд побочных продуктов образуется в радикальных реакциях. Данный механизм описывает кинетику как эпоксидирования так и каталитического разложения гидроперекиси.
    Notes: Abstract The mechanism of the catalytic epoxidation of propylene with α-phenylethyl hydroperoxide has been investigated. The epoxidation step is a molecular interaction between propylene and a complex formed from hydroperoxide and catalyst, while part of side products is formed in free radical reactions. This mechanism is valid for the kinetics of both epoxidation and catalytic decomposition of hydroperoxide.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02071425
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    On the kinetics of the transition metal catalyzed decomposition of secondary hydroperoxides (1981)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 13 (1981), S. 1191-1202 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A general mechanism was proposed for the title reactions which describes the kinetics of hydroperoxide decomposition as well as product accumulation throughout the whole reaction period in an analytical form. The following catalytic steps were included: where the deactivation takes place as a result of radical-catalyst interaction inside the cage. The resulting equations give satisfactory description of the literature data in the case of various catalysts and hydroperoxides.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550131109
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    Paper (German National Licenses)
    Fulltext
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