ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Preparation and Crystal Structure of LnAl3Cl12 (Ln = Tb, Dy, Ho) and Thermal Decomposition to LnCl3LnAl3Cl12 (Ln = Tb, Dy, Ho) was prepared in crystalline form for the first time. The crystal structure of DyAl3Cl12 was determined on single crystals by X-ray methods. DyAl3Cl12 crystallizes with trigonal symmetry, space group P3112, Z = 3. Thermal decomposition of LnAl3Cl12 to the corresponding lanthanide trichloride is described.
Notes:
LnAl3Cl12 (Ln = Tb, Dy, Ho) wurde erstmals in kristalliner Form dargestellt. Die Kristallstruktur von DyAl3Cl12 wurde anhand von röntgenographischen Einkristalluntersuchungen bestimmt. Die Verbindung kristallisiert in der trigonalen Raumgruppe P3112, Z = 3. Der thermische Abbau von LnAl3Cl12 zum entsprechenden Lanthanoidtrichlorid wird beschrieben.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19905860114
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