Library

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
  • 1
    ISSN: 1573-5036
    Keywords: eddy covariance ; eddy accumulation ; micrometeorology ; nitrous oxide
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Measurements of N2O emission fluxes from a 3 ha field of winter wheat were measured using eddy covariance and relaxed eddy accumulation continuously over 10 days during April 1994. The measurements averaged fluxes over approximately 105 m2 of the field, which was fertilised with NH4NO3 at a rate of 43 kg N ha-1 at the beginning of the measurements. The emission fluxes became detectable after the first heavy rainfall, which occured 4 days after fertiliser application. Emissions of N2O increased rapidly during the day following the rain to a maximum of 280 ng N m-2s-1 and declined over the following week. During the period of significant emission fluxes, a clear diurnal cycle in N2O emission was observed, with the daytime maximum coinciding with the soil temperature maximum at 12 cm depth. The temperature dependence of the N2O emission was equivalent to an activation energy for N2O production of 108 kJ mol-1. The N2O fluxes measured using relaxed eddy accumulation, averaged over 30 to 270 min, were in agreement with those of the eddy covariance system within 60%. The total emission of N2O over the period of continuous measurement (10 days) was equivalent to about 10 kg N2O-N, or 0.77% of the N fertiliser applied.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 2
    ISSN: 1573-1480
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The U.K. has extensive databases on soils, land cover and historic land use change which have made it possible to construct a comprehensive inventory of the principal terrestrial sources and sinks of carbon for approximately the year 1990, using methods that are consistent with, and at least as accurate as, the revised 1996 guidelines recommended by IPCC where available – and including categories which are not currently considered under the UN Framework Convention on Climate Change. This country inventory highlights issues concerning methodology, uncertainty, double counting, the importance of soils and the relative magnitude of sources and sinks which are reported to the UNFCCC relative to other sources and sinks. The carbon sinks (negative values in MtC a-1) for categories reported to the UNFCCC, based on the IPCC categories, were estimated to be: forest trees and litter (−2.1), U.K. forest products (−0.5, ignoring imports and exports), non-forest biomass (−0.3), forest soils (−0.1) and soils on set-aside land (−0.4). The carbon sources (positive values) reported under the UNFCCC were estimated to be: losses of soil organic carbon resulting from cultivation of semi-natural land (6.2) and from urbanization (1.6), drainage of peatlands (0.3) and fenlands (0.5), and peat extraction (0.2). A range of other sources and sinks not covered by the IPCC guidelines were also quantified, namely, the accumulation of carbon in undrained peatlands (−0.7, ignoring methane emission), sediment accretion in coastal marshes (−0.1), the possible U.K. share of the CO2 and N fertilization carbon sink (−2.0) and riverine organic and particulate carbon export to the sea (1.4, which may be assumed to be a source if most of this carbon is released as CO2 in the sea). All sinks totalled −6.2 and sources 10.2, giving a net flux to the atmosphere in 1990 of 4.0 MtC a-1. Uncertainties associated with categories, mostly based on best guesses, ranged from ±15% for forest biomass and litter to ±60% for CO2 and N fertilization.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 3
    ISSN: 1573-0662
    Keywords: air pollution ; field study ; modelling ; atmospheric chemistry ; troposphere ; clouds ; nitrogen compounds ; NO x ; NO3 ; N2O5 ; NO3 - ; NO2 - ; HNO3 ; HNO2
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract Four case studies are described, from a three-site field experiment in October/November 1991 using the Great Dun Fell flow-through reactor hill cap cloud in rural Northern England. Measurements of total odd-nitrogen nitrogen oxides (NO y ) made on either side of the hill, before and after the air flowed through the cloud, showed that 10 to 50% of the NO y , called NO z , was neither NO nor NO2. This NO z failed to exhibit a diurnal variation and was often higher after passage through cloud than before. No evidence of conversion of NO z to NO3 - in cloud was found. A simple box model of gas-phase chemistry in air before it reached the cloud, including scavenging of NO3 and N2O5 by aerosol of surface area proportional to the NO2 mixing ratio, shows that NO3 and N2O5 may build up in the boundary layer by night only if stable stratification insulates the air from emissions of NO. This may explain the lack of evidence for N2O5 forming NO3 - in cloud under well-mixed conditions in 1991, in contrast with observations under stably stratified conditions during previous experiments when evidence of N2O5 was found. Inside the cloud, some variations in the calculated total atmospheric loading of HNO2 and the cloud liquid water content were related to each other. Also, indications of conversion of NO x to NO z were found. To explain these observations, scavenging of NO x and HNO2 by cloud droplets and/or aqueous-phase oxidation of NO2 - by nitrate radicals are considered. When cloud acidity was being produced by aqueous-phase oxidation of NO x or SO2, NO3 - which had entered the cloud as aerosol particles was liberated as HNO3 vapour. When no aqueous-phase production of acidity was occurring, the reverse, conversion of scavenged HNO3 to particulate NO3 -, was observed.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...