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  • 1
    Electronic Resource
    Electronic Resource
    Measurement of the photodissociation coefficient of NO2 in the atmosphere: I. Method and surface measurements (1983)
    Springer
    Journal of atmospheric chemistry 1 (1983), S. 3-25 
    Details
    ISSN: 1573-0662
    Keywords: J NO 2 ; NO2 photolysis ; atmospheric photochemistry ; J NO 2measurement
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract An instrument, specifically designed for measurements from a balloon platform in the stratosphere, has been used to obtain ground-level values of the atmospheric photodissociation coefficient of nitrogen dioxide, J NO 2.A typical clear-sky value is 8.0×10-3 s-1 when the solar zenith angle is 40°. Measurements were made as a function of solar zenith angle and correlated with a calibrated Eppley UV radiometer. It is shown that J NO 2may be expressed as a simple function of the radiometer output so that estimates of J NO 2can be made using just an upward looking radiometer to an accuracy of about 20%. The measurements are also found to be in good agreement with calculations of J NO 2using a simplified isotropic multiple scattering computer routine.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00113977
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Calculations of the temperature dependence of the NO2 photodissociation coefficient in the atmosphere (1984)
    Springer
    Journal of atmospheric chemistry 1 (1984), S. 151-157 
    Details
    ISSN: 1573-0662
    Keywords: Atmosphere ; photolysis ; nitrogen dioxide ; photodissociation coefficient ; temperature effect
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract The photodissociation coefficient, J NO2 of NO2 in the atmosphere was calculated at 235 and 298 K using the measured temperature dependences of the absorption cross-sections and quantum yields. These calculations gave a ratio J NO2(298 K)/J NO2(235 K)=1.155±0.010 which is only weakly dependent on altitude, surface albedo and solar zenith angle.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00053837
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    Measurement of the photodissociation coefficient of NO2 in the atmosphere: II, stratospheric measurements (1985)
    Springer
    Journal of atmospheric chemistry 3 (1985), S. 233-245 
    Details
    ISSN: 1573-0662
    Keywords: J NO 2 ; NO2 photolysis ; atmospheric photochemistry ; J NO 2 measurement
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract The photodissociation coefficient of NO2, J NO 2, has been measured from a balloon platform in the stratosphere. Results from two balloon flights are reported. High Sun values of J NO 2 measured were 10.5±0.3 and 10.3±0.3×10-3 s-1 at 24 and 32 km respectively. The decrease in J NO 2 at sunset was monitored in both flights. The measurements are found to be in good agreement with calculations of J NO 2 using a simplified isotropic multiple scattering computer routine.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00210498
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    Paper (German National Licenses)
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  • 4
    Electronic Resource
    Electronic Resource
    The reactions of ozone with methyl and ethyl nitrites (1976)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 8 (1976), S. 307-313 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The reactions of O3 with CH3ONO and C2H5ONO were studied using infrared absorption spectroscopy in a static reactor at temperatures between 298 and 352K. Both reactions followed simple second-order kinetics forming the corresponding nitrate: The rate coefficients are given by \documentclass{article}\pagestyle{empty}\begin{document}$$\log _{10} {\rm}k_1 ({\rm cm}^{\rm 3} /{\rm molc} \cdot {\rm sec}) = (- 12.17 \pm 0.23) - (\frac{{5315 \pm 172}}{{2.303{\rm}T}})$$\end{document} \documentclass{article}\pagestyle{empty}\begin{document}$$\log _{10} {\rm}k_2 ({\rm cm}^{\rm 3} /{\rm molc} \cdot {\rm sec}) = (- 15.50 \pm 0.16) - (\frac{{2351 \pm 116}}{{2.303{\rm}T}})$$\end{document}.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550080212
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    Paper (German National Licenses)
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