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  • 1
    ISSN: 1612-1112
    Keywords: Supercritical fluid chromatography ; Column liquid chromatography ; Polycyclic aromatic hydrocarbons ; Environmental samples
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The separation in 6 minutes of the sixteen US Environmental Protection Agency (EPA) polycyclic aromatic hydrocarbons (PAHs) on a single packed column by supercritical fluid chromatography (SFC) is described and compared to that obtained using liquid chromatography with the same column. Several environmental samples containing polycyclic aromatic hydrocarbons obtained from various sources including soil, water, petrochemicals and coal have been analysed by SFC under optimised conditions. Packed column SFC is shown to be an efficient and promising method for the rapid monitoring of environmental polycyclic aromatic hydrocarbons.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    ISSN: 1612-1112
    Keywords: Supercritical fluid chromatography ; Molecular mechanics ; Chiral stationary phase ; Matrix interaction
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A model is devised using molecular mechanics to simulate chromatographic separations of enantiomers. Theoretical results derived from this model are compared with experimental findings obtained using supercritical fluid chromatography. The model is then developed to incorporate the effects of binding the stationary phase to a matrix. Computed results show that addition of the matrix into the model has significant effects on the ability of the stationary phase to separate racemic mixtures.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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