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  • 1
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 278 (1979), S. 542-545 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] If bicarbonate is still present, simply measuring alkalinity will not reveal whether or not acidification has occurred unless pre-acidification alkalinity data are available for comparison. Unfortunately, few such data exist. However, in unacidified waters bicarbonate alkalinity is present in ...
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Copenhagen : International Union of Crystallography (IUCr)
    Acta crystallographica 52 (1996), S. 730-737 
    ISSN: 1399-0047
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: The structure of a trigonal crystal form of porcine pancreatic spasmolytic polypeptide (PSP) has been solved by molecular replacement and refined to 1.95 Å resolution. Three heavy-atom derivatives were prepared, giving unbiased phase information, which was used in the model building of the protein molecules. The final conventional R value is 19.8% with the inclusion of 183 water molecules. PSP crystallizes as a dimer in space group P3121 with a non-crystallographic twofold axis relating the monomers. The monomer consists of two very similar domains each composed of three loop regions. Two clefts are found in the monomer, one in each domain, that are proposed as possible substrate-binding sites. Important interactions have been identified in the proposed substrate-binding sites, where conserved water molecules probably mimic the hydrophilic positions of the substrate. The estimated cleft size is 9 × 9 × 12 Å. Analysis of the charge distribution within the clefts, by an electrostatic potential calculation, shows the clefts to be essentially non-charged.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Copenhagen : International Union of Crystallography (IUCr)
    Acta crystallographica 51 (1995), S. 121-123 
    ISSN: 1399-0047
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: A non-glycosylated form of horseradish peroxidase c extracted from Escherichia coli inclusion bodies and refolded in the presence of haem and Ca2+ ions has been used to grow protein crystals suitable for X-ray diffraction analysis. The crystals are prisms in the trigonal space group P3112 or P3212 with a = b = 158.9 and c = 114.3 Å, and diffract to 1.9 Å. There are four molecules, each of 34 kDa, in the asymmetric unit. The molecules of the asymmetric unit are related by approximate translational symmetry, resulting in pseudo-centerings. Data to approximately 15 Å can thus be described by a lattice of a′ = b′ = 91.7 Å and c′ = 57.1 Å, α = β = 90° and γ = 120°, including four molecules.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 0014-4827
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology , Medicine
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Biochimica et Biophysica Acta (BBA)/General Subjects 421 (1976), S. 348-352 
    ISSN: 0304-4165
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Biology , Chemistry and Pharmacology , Medicine , Physics
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Chemometrics and Intelligent Laboratory Systems 14 (1992), S. 331-339 
    ISSN: 0169-7439
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 372 (1994), S. 327-328 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] SIR - Acidification of rivers and lakes has caused decline in fish stocks in many areas affected by man-made emissions of sulphur dioxide and nitrogen oxides1. Deaths of fish typically occur in acid 'episodes', when there is high runoff from the surface of acid soils. In addition to ...
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 305 (1983), S. 422-424 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Our method of prediction derives from empirical relationships between sulphur deposition, water chemistry and fisheries status for several thousand lakes and rivers in Europe and North America4'5. The method takes into account lake-to-lake differences in sensitivity, changes in base cation ...
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 85 (1995), S. 629-634 
    ISSN: 1573-2932
    Keywords: acidification ; monitoring ; calibrated catchments ; lakes ; rivers ; ground water
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Surface and ground water monitoring in Norway is designed to give a regional coverage with most of the stations in areas with acidification and some stations in unpolluted areas that give background values. Surface water (weekly sampling) and precipitation (daily measurement) are monitored at 6 calibrated catchments, 5 located in southern Norway and 1 in northernmost Norway close to the Russian border. Ground water (weekly sampling) is monitored in 4 reservoirs in Southern Norway. 73 lakes located all over Norway are surveyed each fall. Nineteen rivers in western and southern Norway are monitored by monthly sampling. All sites are considered sensitive to acidification and are chosen to minimise the effects of anthropogenic catchment based impacts. Results from the monitoring over the period 1980–1994 show that there is a reduction of sulphate of about 25–35% in surface waters which is related to a 30–45% reduction in sulphate concentration in precipitation. An improvement in water quality as measured as increase in ANC has only been apparent since 1990. Due to heavy seasalt episodes in the most coastal catchments like Birkenes and the rivers in western Norway, there has been no improvement of ANC since 1980. Deposition of nitrogen has not changed over the last 10 years, and there is no change in the levels of nitrate in the monitored surface waters.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 85 (1995), S. 2419-2424 
    ISSN: 1573-2932
    Keywords: critical load ; acidity ; water acidification ; soil acidification ; fish ; empirical models ; sulphur deposition ; acid episodes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The critical load of acidity for surface waters is based on the concept that the inputs of acids to a catchment do not exceed the weathering less a given amount of ANC. The Steady State Water Chemistry (SSWC) Method is used to calculate critical loads, using present water chemistry. To ensure no damage to biological indicators such as fish species a value for ANClimit of 20 μeq/l has been used to date for calculating critical loads. The SSWC-method is sensitive to the choice of the ANClimit. In areas with little acid deposition the probability of acid episodes leading to fish kills is small even if the ANClimit is set to zero, while in areas with high acidic deposition fish kills may occur at this value. Thus, the ANClimit can be a function of the acidifying deposition to the lake, nearing zero at low deposition and increasing to higher values at higher deposition. A formulation for such an ANClimit has been worked out, and we have tested the effect of the ANClimit as a linear function of the deposition, assuming ANClimit = 0 at zero deposition with a linear increase to 50 ueq/l at a deposition of 200 meq.m−2.yr−1. For areas with high deposition the effect of a variable ANClimit is small, while in areas with low deposition the effect is significant. For Norway the exceeded area decreases from 36 to 30% using a variable ANClimit instead of a fixed value of 20 μeq/l.
    Type of Medium: Electronic Resource
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