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  • 1
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 81 (1998), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: PbO-BiO1.5-GaO1.5-based glasses are good candidates for optical applications, because of some of their interesting characteristics, such as high refraction indices and high transmission in the ultraviolet (UV), visible (VIS), and infrared (IR) regions. A limited stage in the processing of these glasses is the corrosion that is caused by the melt in all currently used conventional crucibles, such as noble metals (platinum or gold) and Al2O3. The absorption of crucible material by the glass composition may reduce the transmission level, the cutoff in the UV-VIS, and IR regions, and the thermal stability. In this study, a SnO2 crucible has been tested for PbO-BiO1.5-GaO1.5 molten glass. Optical and thermal analyses show, in some cases, advantages over the use of platinum and Al2O3 crucibles. A visible cutoff value of 474 nm has been measured, and a longer melting time (850°C for 4 h) results in a significant reduction of the O-H absorption band at 3.2 μm.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 85 (2002), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A solid-state route to synthesize bismuth germanate (Bi4Ge3O12, or BGO) ceramics, and the optimum conditions for the laser sintering of these ceramics, were investigated. Special emphasis was placed on the influence of laser power and irradiation time on densification and microstructure evolution. The procedure that was used involved preheating the samples and a laser-irradiation program, which resulted in sintered, crack-free BGO ceramics with good pore shrinkage and a relative density of 95% (±3%).
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 87 (2004), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: We have investigated the potential use of Bi4Ge3O12 (BGO) laser-sintered ceramics in scintillator devices for radiation detection. Relevant results from the characterization made during the ceramic processing are presented, such as particle size analysis, X-ray diffraction studies, and thermal analysis. Furthermore, we have compared the microstructure, relative density, thermoluminescent (TL) emission, and transparency degree of ceramic bodies sintered by CO2 laser heating with a reference set of ceramics sintered in an electrical furnace, and also with single crystals grown by the Czochralski technique. It was observed that the laser-sintered BGO presented a relative density of 98% (±2%), better pore shrinkage, larger grains, and light transmission intensity 1.5 times higher than the BGO ceramics sintered in a furnace. The TL curves of all samples irradiated with UV and β−rays presented peaks at 75°, 102°, and 143°C, and provided strong indication that the intergrain defects have the same nature of the bulk defects and do not contribute with new traps in the temperature range studied. The relative areas of the total TL emission after β irradiation were 6,0:4,4:1 for the reference ceramic, laser sintered ceramic, and single crystal, respectively. For UV irradiated samples, this relation was 7,1:4,7:1. From these results, we have concluded that laser-sintered ceramics have an amount of charge traps lower than the conventionally sintered BGO samples, thus having a higher radioluminescence yield.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Materials science forum Vol. 455-456 (May 2004), p. 665-670 
    ISSN: 1662-9752
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Materials science forum Vol. 514-516 (May 2006), p. 1216-1220 
    ISSN: 1662-9752
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: We have studied the synthesis and sintering of BaTiO3 (BTO) nanometric powdersproduced by Pechini technique. A laser sintering procedure was applied to the BTO and its majoradvantage was the quickness of the processing. We have used the radiation of a CO2 laser (CW –100 W) as the heating source. A linear rate of irradiation was applied to avoid macroscopic defects.The calcined powder at 800°C presented a single crystalline phase confirmed by the XRD and acrystallite size of 20 nm. BTO ceramics sintered at Pmax = 7.0 W/mm2 for 10 min of irradiationshowed a high relative density (98 ± 1) % with an average grain size of 400 nm for a total time ofsintering of 40 minutes
    Type of Medium: Electronic Resource
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