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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 78 (1995), S. 5277-5282 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Phosphorescent light emission was investigated upon irradiation of WF6/H2/noble gas (Ar, Kr, Ne, Xe) mixtures by ArF excimer laser. The continuous, broadband phosphorescence emission originates from excited tungsten clusters. The phosphorescence ceased with increased Xe and H2 concentrations. Xe inhibits the formation of tungsten clusters and H2 quenches the phosphorescence. The H2 quenching rate and the unperturbed phosphorescence lifetime were determined to be 2.8×104 mbar−1 s−1 and 23 μs, respectively. The intensity dependence of phosphorescence on the WF6 partial pressure shows a rising part, then a declining part, and finally an increasing part again. It was shown that the declining part can be interpreted by scattering of the emitted phosphorescence. The phosphorescence intensity was dependent on the noble gas/H2 concentration ratio. This effect was explained in terms of the thermal conductivity of the WF6/H2/noble gas mixture, which influences the lifetime of the activated subfluorides and, thus, the cluster formation and growth rate. The intensity of the laser beam had a nonlinear effect on the phosphorescent light intensity due to the nonlinearly coupled photolytical steps of WF6 and of the subfluorides. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 107 (1997), S. 10440-10445 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Continuous, black-body-type light emission is observed upon irradiation of gas phase C60 and C70 by 193 nm ArF excimer laser at fluences from 3 to 80 mJ/cm2 in Ar and He ambient. Cluster temperatures are estimated by calibrating the detection system against a tungsten filament and applying Wien's displacement law. Time-resolved spectroscopic measurements show that the initial internal temperature of the irradiated fullerenes (around 2800 K) decreases linearly, while the emitted light intensity decreases exponentially with time, respectively. Excited C60 and C70 molecules are predominantly cooled via inelastic collisions with noble gas atoms above ∼0.5 mbar ambient pressure and below ∼2800 K temperature. The quenching rates are ∼7.1 bar−1 s−1 for C60, and ∼6.4 bar−1 s−1 for C70 in Ar, and 81 bar−1 s−1 for C60 in He ambient, respectively, determined from Stern–Vollmer type relations. The inelastic quenching cross section for He gas (∼4.4×10−23 cm2) is ∼3.7 times higher than for Ar. This observation may provide further insight on the mechanisms of fullerene synthesis by coalescence of hot carbon vapor in a noble gas atmosphere. At laser fluence above 30–40 mJ/cm2 the fullerene temperature saturates at ∼2800 K, indicating a kind of phase-transition—"boiling" of the excited fullerenes. The cluster temperature stabilizes by other cooling mechanisms like electron and/or C2 "evaporation" (i.e., ionization and/or fragmentation). The unperturbed (i.e., extrapolated to zero ambient pressure) lifetime of the temperature-stabilized species is 100±25 μs for C60 and 44±4 μs for C70, respectively, at high (80 mJ/cm2) laser fluences. The measured two- and three-photon multiplicities of the excitation at low laser fluences (〈15 mJ/cm2) are in good agreement with the observed cluster temperatures. © 1997 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 89 (2001), S. 3967-3970 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Recently we reported that phosphorescent light emission was observed upon irradiation of WF6/H2/noble gas (Ar, Kr, Ne, Xe) mixtures by ArF excimer laser [P. Heszler, P. Mogyorósi, and J.-O. Carlsson, J. Appl. Phys. 78, 5277 1995], originating from tungsten nanoparticles. In this work results of additional measurements on the same system are presented, and we conclude that the reported phosphorescence is a blackbody-like radiation. Taking into account the emissivity of the particles calculated on the base of the Mie theory, it was possible to determine the dependence of the temperature of the tungsten nanoparticles on time after the laser pulse by means of time-resolved spectroscopy. It is shown that surface reactions on the hot nanoparticles contribute significantly to the growth. The size distribution was found lognormal by transmission electron microscopy measurements. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Applied Surface Science 69 (1993), S. 272-276 
    ISSN: 0169-4332
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Applied Surface Science 69 (1993), S. 376-379 
    ISSN: 0169-4332
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Solid State Communications 78 (1991), S. 425-427 
    ISSN: 0038-1098
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy Section 48 (1992), S. 41-44 
    ISSN: 0584-8539
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 49 (1989), S. 739-740 
    ISSN: 1432-0630
    Keywords: 82.35 ; 81.60 ; 61.80B
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract The incubation process in polyimid was investigated at 337.1 nm UV photoablation. The threshold number of incubation pulses needed to start the ablation is proportional to a reciprocal cubic function of the fluence and does not depend on the repetition rate of the laser between 0 and 20 pps. A simple model is presented to explain these characteristics.
    Type of Medium: Electronic Resource
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  • 9
    ISSN: 1432-0630
    Keywords: PACS: 61.80.B; 61.16.C; 78.30; 68.55
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: 2 fluence results in the formation of a thin hydrogen-free diamond-like carbon (DLC) film on the surface. The density of the laser-formed DLC layer is approximately 2.8 g/cm3, as calculated from area-selective Raman spectroscopy and atomic force microscopic (AFM) measurements. The proportion of the sp3 hybrid states of carbon is estimated to be approximately 50%. Annealing in air at 650 °C for 30 min recovers the graphite structure.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 1432-0630
    Keywords: PACS: 43.25.Cb; 61.80
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract. Highly oriented pyrolytic graphite (HOPG) was ablated by a 193-nm ArF excimer laser in air. The fluence was varied in the range 1–25 J/cm2. Every laser shot hit a pristine graphite surface. The emerging shock wave was recorded by a nanosecond-resolution photographic arrangement. The velocity of the shock wave as a function of time and laser fluence was measured. The amount of energy that generates the shock wave was determined and found to be about 5–7% of the incident laser energy. The shock wave is already present 10–15 ns after the maximum of the incident laser pulse. These facts imply that, even if high-energy (10–100 eV) ions, atoms, or clusters leave the surface, a layer several 10 nm thick has to be removed during this short period. The temperature of the shock front is ∼2500–4000 K, as derived from the measured velocities. Measuring the ablation depth by atomic force microscopy as a function of fluence revealed that the single-shot ablation threshold is 1.4±0.2 J/cm2, and the effective absorption coefficient is ∼1.5×105 cm-1.
    Type of Medium: Electronic Resource
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