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1,2,4,5-Tetrazine: Synthesis and Reactivity in [4+2] Cycloadditions (1998)

Sauer, Jürgen ; Heldmann, Dieter K. ; Hetzenegger, Josef ; [et al.]

Weinheim : Wiley-Blackwell

Liebigs Annalen 1998 (1998), S. 2885-2896

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ISSN: 1434-193X

Keywords: Alkenes ; Alkynes ; Cycloadditions ; Nitrogen heterocycles ; Tetrazines ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Full details on the reactivity of the title compound as 4π component in inverse-type Diels-Alder reactions, including kinetic data, are reported. Donor-substituted alkynes, alkenes, donor-substituted and unsubstituted cycloalkenes, ketene acetals and aminals, as well as several cyclic enol ethers were used as dienophiles in these investigations. A number of 4-mono- and 4,5-disubstituted pyridazines can easily be obtained by this method.

Additional Material: 5 Ill.

Type of Medium: Electronic Resource

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