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Quinones, 11 Synthesis of 3,7-Di-tert-butyl-9,10-dimethyl-2,6-anthraquinone (1987)

Boldt, Peter ; Hilmert-Schimmel, Petra ; Müller, Renate ; [et al.]

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 120 (1987), S. 497-500

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ISSN: 0009-2940

Keywords: Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Description / Table of Contents: Ein nur durch Alkylgruppen stabilisiertes 2,6-Anthrachinon, 3,7-Di-tert-butyl-9,10-dimethyl-2,6-anthrachinon (7), konnte erstmals synthetisiert werden. Die Stellung der Alkyl-Schutzgruppen wurde auf Grund einfacher MO-Betrachtungen bestimmt.

Notes: A 2,6-anthraquinone only stabilized by alkyl groups, 3,7-di-tert-butyl-9,10-dimethyl-2,6-anthraquinone (7), has been synthesized for the first time. The positions of the alkyl shielding groups has been determined on the basis of simple MO considerations.

Additional Material: 1 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19871200408

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