Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
90 (1989), S. 6821-6826
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
Vacuum ultraviolet fluorescence excitation spectra of jet cooled ICl have been recorded between 158 and 166 nm using a VUV "laser'' generated by four-wave sum-mixing in Mg vapor. An unambiguous vibrational analysis of the spectra has shown that transitions from v‘=0 of the ground state probe high vibrational levels of the first tier EO+ ion-pair state between v'=245 and 360. Molecular constants obtained from both Dunham and near dissociation expansions are presented. Strong intensity modulation of the spectra was observed. Possible reasons for this effect are discussed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.456254
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