ISSN:
1572-8854
Source:
Springer Online Journal Archives 1860-2000
Topics:
Geosciences
,
Physics
Notes:
Abstract Cis-mesityl(phenylsulphonyl)sulphine, C16H16O3S2, crystallizes in the tri-clinic system: space groupP¯1,a = 9.209(2),b = 11.106(2),c = 7.626(1) Å, α = 92.53(1), β = 98.53(3), γ = 89.82(2) °. The structure has been determined by Patterson and direct methods and refined by full-matrix least squares toR = 0.057 for 2724 observed reflections. The sulphine moiety has bond lengths 1.622(2) Å for C-S, 1.466(3) Å for S-O and a C-S-O angle of 115.2(2) °, indicating sp2 hybridization on the sulphur atom. All other bond distances and angles are close to normal values. The molecules are held together by van der Waals forces.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01374436
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