ISSN:
0935-6304
Keywords:
Capillary GC
;
Fused silica columns
;
Peak splitting
;
Christmas tree peaks
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Fluctuating thermal gradients are recognized as a distinct source of peak splitting in capillary column gas chromatography. In this study, the influence of analyte signal level, temperature oscillation amplitude, and oscillation frequency on splitting are quantitatively examined. Stable gradients are also considered. A simple, effective method is proposed for virtually eliminating thermal peak splitting in isothermal capillary GC analysis.
Additional Material:
7 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jhrc.1240090605
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