ISSN:
0894-3230
Keywords:
N,N′-dicyclohexyl-O-(1-methylheptyl)isourea
;
OH-acidic compounds
;
acetic acid
;
kinetics
;
mechanisms
;
Chemistry
;
Theoretical, Physical and Computational Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
Kinetic investigations on the reaction of N,N′-dicyclohexyl-O-(1-methylheptyl)isourea with acetic acid are described. The conversion proceeds partly through the intermediacy of a methylheptylcarbenium ion. However, in dilute solution an SN2 mechanism prevails. The results are discussed in terms of the simultaneous existence of two discrete mechanisms. © 1998 John Wiley & Sons, Ltd.
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
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