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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Macromolecules 13 (1980), S. 1280-1289 
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Macromolecules 23 (1990), S. 268-276 
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Macromolecules 25 (1992), S. 6681-6689 
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Macromolecules 26 (1993), S. 5790-5795 
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Langmuir 8 (1992), S. 1170-1175 
    ISSN: 1520-5827
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 92 (1990), S. 3206-3212 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Using the lubrication approximation, we calculate the dynamics of a contact line on a periodic heterogeneous plate which is advanced at constant force F or constant velocity u. For a constant force, motion starts when F exceeds a threshold Fc which is simply related to the static advancing (receding) contact angle. If the heterogeneity is smooth, the force increases with velocity as F−Fc∝u2. Alternating patches of constant wettability produce a linear relation. For constant velocity experiments, we identify weak and strong pinning regimes. In the weak pinning regime, the threshold force is zero and the force–velocity relation approaches that of a uniform surface. In the strong pinning regime, the threshold F0 is finite and approaches Fc as the strength of the heterogeneity increases. For smooth heterogeneity, F−F0∝u2/3, while alternating patches produce a linear response. The relevance of these results to experimental surfaces with random heterogeneity is discussed.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 98 (1993), S. 1647-1658 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We study some dynamical aspects of grafted polymer layers in a solvent. The structure of the brush is described in a θ solvent by the self-consistent mean field theory and in a good solvent using scaling laws. The Rouse–Zimm model including hydrodynamic interactions is used for the dynamic properties. A given chain end explores the entire thickness of a free grafted layer in a time Te proportional to the cube of the thickness. The exploration time is much larger than the Rouse time that characterizes the relaxation of the fluctuations of the chains conformations. In a θ-solvent we give a detailed study of the relaxation of the density of a few labeled chain ends towards its equilibrium value. The bridging kinetics between a grafting plate and a plate adsorbing the free ends is also discussed. When adsorption proceeds, an exclusion zone grows in the vicinity of the adsorbing plate. To cross the exclusion zone and adsorb, a chain end must overcome an energy barrier. The typical adsorption time is the first passage time through this barrier. Except in the very late stages where the fraction of chains η forming bridges saturates at its equilibrium value, the energy barrier against adsorption increases as a power law of η and the bridging fraction increases very slowly (logarithmically) with time. Both weak bridging where only a small fraction of chains form bridges and total bridging where all the chains form bridges are studied.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 101 (1994), S. 4379-4390 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We discuss the dynamic properties of a semidilute grafted polymer layer exposed to pure solvent. When the grafting energy of the head groups of the chains is finite, the chains desorb and are expelled from the layer. We combine Monte Carlo simulations using the bond fluctuation model to self-consistent mean field calculations and a scaling analysis. Chain desorption can be seen as a two step process. For strongly grafted polymers the limiting step is the desorption of the head group. The chain is then expelled by the osmotic pressure gradient. A chain cut off the wall is expelled at a constant velocity of its center of mass. The velocity decreases as the inverse of the molecular weight and increases with the grafting density. In the early stages of the expulsion the tension of the monomers close to the wall relaxes and the chain retracts. The retraction is independent of the molecular weight. Our most important result is that the desorption of the head group is a local process with a characteristic time independent of molecular weight. The desorption time increases exponentially with the grafting energy, it decreases as a power law of the grafting density. The exponent is close to 2 but the precise value is difficult to extract from the simulation.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 101 (1994), S. 9181-9194 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We analyze the adsorption of flexible polymers between two parallel plates separated a distance 2l. We consider a semidilute polymer solution in contact with the two adsorbing walls and describe the statistics of bridges and loops. A detailed mean-field calculation allows us to obtain the size and density of bridges in two regimes: l(approximately-greater-than)ξ and l〈ξ, where ξ is the bulk correlation length, as well as the size of loop and train sequences. These results are compared with a scaling analysis performed in the spirit of the self-similar profile introduced by de Gennes.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 97 (1993), S. 4825-4831 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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