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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial and engineering chemistry 1 (1962), S. 285-292 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of chemical & engineering data 6 (1961), S. 496-498 
    ISSN: 1520-5134
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Wood science and technology 11 (1977), S. 225-236 
    ISSN: 1432-5225
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Summary A technique was developed for the determination of the effective dissolved oxygen diffusivity in liquid-saturated softwood in a diffusion cell under ambient pressure. From the measurements in the temperature range 2° to 50°C, the activation energy of diffusion was found to be 4.6 kcal/mole. The diffusivity in summerwood is about one half of that in springwood. The diffusivity of dissolved oxygen through composite springwood and summerwood layers was based upon samples of two Douglas fir sapwood blocks saturated with water. In the radial and tangential directions, diffusivity was 1.4 to 2.3x10-6cm2/s, which is about 6 to 10% that of dissolved oxygen diffusivity in water. The diffusivity in the longitudinal direction is about 5.5 times that in the other two directions. The diffusivity of dissolved oxygen through liquor-saturated wood and the effect of delignification on oxygen diffusion were also determined.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 17 (1971), S. 981-983 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Rates of the dehydration of methanol to dimethyl ether catalyzed by cation exchange resin (polystyrenesulfonic acid) were measured with a differential flow reactor and gas chromatographic analysis. Reaction temperature was 119°C., pressure was 1 atm., and feeds were methanol and mixtures of methanol with argon, dimethyl ether, and water.Rata data for the methanol reaction as well as the previously investigated ethanol dehydration reaction are well represented by Langmuir-Hinshelwood kinetics with adsorption parameters in the rate equations approximately equal to corresponding values of Langmuir adsorption equilibrium constants estimated from or available in the literature. The reaction model is consistent with previous conclusions regarding mechanism. Its pertinence suggests that at reaction conditions the ion exchange resin offers a nearly homogeneous array of catalytic sites.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 4 (1958), S. 445-452 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Some characteristics of gas pockets rising through beds of fluidized solids have been measured directly with a light probe technique. The vertical thickness, numerical frequency, and rate of rise of the bubbles were obtained from oscillographs of dual probe signals. Room-temperature air at 1-atm. pressure was used in 4- and 6-in. columns. Glass beads, a crushed rock, commerical cracking catalysts, coal, and hollow resin spheres were studied in particle sizes from 12-µ fluid cracking catalyst to 450-µ coal.Vertical bubble thickness was found to increase with particle size, distance above the bed support, and gas velocity. Size growth upon rising was mainly the result of coalescence of bubbles. The rise velocity ranged from 1 to 2 ft./sec., relatively unaffected by operating conditions. Bubble frequency decreased with height above the bed support owing to coalescence. Total bed-depth variation from 1.0 to 2.5 ft. did not significantly influence the results, which should be of interest in studying gas by-passing in fluidized beds and predicting the slugging behavior and fluidization uniformity.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
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