Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
106 (1997), S. 10105-10112
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
The photodissociation of the SiO molecule, which is of considerable astrophysical interest, is studied within the framework of the Floquet theory. Only the one-photon transition process between the two lowest 1Σ+ states is considered. The computation of the electronic energy surfaces is performed with the MOLPRO code. The wave operator theory is used to select the active space related to this process, and to build the Floquet resonance states which constitute this active space. Particular attention is paid to the role of the shape resonance states induced by the presence of a barrier on the E 1Σ+ surface. © 1997 American Institute of Physics.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.474044
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