Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
97 (1992), S. 9099-9106
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
The photodissociation of jet-cooled HgI2 has been studied in the 244–323 nm region using a tunable ultraviolet (UV) laser. Dispersed emission, action, and multiphoton ionization spectra have been recorded. A vibrational analysis of the action spectra near 305 nm shows that the production of excited Hg atoms from HgI2 UV photodissociation proceeds through a HgI ground-state intermediate. Near 248 nm the results are less conclusive. Possible reasons for a wavelength-dependent kinetic mechanism are discussed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.463337
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