ISSN:
0887-624X
Keywords:
phenolphthalein-N-(methylanilide)
;
spectral analysis
;
terephthaloyl chloride, cardo polyesters
;
thermal properties
;
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
New phthalide-containing bisphenols, phenolphthalein-N-(3-methylanilide) (3-PMA), and phenolphthalein-N-(4-methylanilide) (4-PMA), were synthesized from phenolphthalein and m- and p-toluidines. These bisphenols were polycondensed with terephthaloyl chloride (TPC) using an interfacial or solution polymerization technique to yield new polyesters. Copolymers were also obtained by utilizing different molar proportion of phenolphthalein (PPH) and 3-PMA or 4-PMA with TPC. The polymers prepared by solution polymerization were obtained in 93-99% yields and showed reduced viscosities in the range 0.37-0.83 dL/g. They were readily soluble in chlorinated hydrocarbons and aprotic polar solvents. The polyesters showed glass transition temperatures in the range 261-300°C as measured by DSC. Thermogravimetric analysis of the polyesters indicated no weight loss below 408°C under N2 atmosphere. Structure-property correlations among these cardo polyesters have been discussed. © 1997 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 35: 3227-3234, 1997
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
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