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  • 1
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Weed research 35 (1995), S. 0 
    ISSN: 1365-3180
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: A newly developed chemical assay was used to determine the degradation in soil of two sulfonylurea herbicides, primisulfuron-methyl and metsulfuron-methyl, under both controlled and field conditions. The results from the chemical assay were compared with those from traditional bio-assays for determination of persistence in the field. Phytotoxic effects of these herbicides were not observed after 6 weeks following application to an acidic (pH 5.7) soil with high organic matter content (7.3% o.c). Half-lives of 13 to 29 days were measured for primisulfuron-methyl at different soil-water contents and temperatures while those for metsulfuron-methyl ranged from 8 to 36 days. The rate of degradation of metsulfuron-methyl was more sensitive to temperature than that of primisulfuron-methyl. Persistence in the field was shorter than expected considering the results from the controlled environment studies. However, determination of the persistence by both chemical assay and bioassay methods produced very similar results.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Fresenius' Zeitschrift für analytische Chemie 339 (1991), S. 151-157 
    ISSN: 1618-2650
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A simple method for the determination of several thermolabile carbamate and urea pesticides as acetyl derivatives by means of capillary gas chromatography is described. 10 carbamate and 6 urea pesticides yielded thermostable derivatives which can easily be analysed by GC-MSD at the relevant residue levels as demonstrated with food samples. The method was designed to be used in addition to a popular multimethod (S19 — DFG Pesticide Commission).
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Fresenius' Zeitschrift für analytische Chemie 339 (1991), S. 40-45 
    ISSN: 1618-2650
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The determination of urea pesticides is difficult by means of gas chromatography because they undergo thermal decomposition when applying standardized chromatographic conditions as used in multiresidue analysis. A method is therefore described to make possible the detection of these compounds by gas chromatography after derivatization with HFBA using either electron capture and nitrogen-phosphorus detection or a mass spectrometer as detector.
    Type of Medium: Electronic Resource
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