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Kinetics of polymerization of vinyl monomers initiated by lead tetraacetate (1986)

Balakrishnan, T. ; Kasilingam, E. K.

Bognor Regis [u.a.] : Wiley-Blackwell

Journal of Polymer Science Part A: Polymer Chemistry 24 (1986), S. 1747-1752

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Details

ISSN: 0887-624X

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: A systematic study of the thermal polymerization of α-chloroacrylic acid and α-bromoacrylic acid in aqueous nitric acid was carried out. The effect of variation of monomer concentration lead tetraacetate concentration, hydrogen ion concentration, ionic strength, and temperature on the rate of monomer disappearance was carried out. Based on the experimental observations, suitable reaction schemes were proposed for the polymerization of the above monomers. The rate constants and the thermodynamic parameters were evaluated.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pola.1986.080240803

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