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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 90 (1989), S. 1544-1550 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We report a vibrationally resolved dispersed fluorescence study of 7σ−1 shape resonant photoionization in N2O. Previous work indicates that there are two shape resonances in the εσ channel, and our results demonstrate that the lower energy shape resonance (hνexc≈20 eV) results in non-Franck–Condon vibrational branching ratios over a wide range. Moreover, the cross section curves for alternative vibrational modes behave differently, and we show that the symmetric stretch exerts a greater influence on resonance behavior than the asymmetric stretching vibration. Such comparisons of vibrationally resolved partial cross section curves provide qualitative insights into the shape resonant photoionization dynamics for polyatomic targets. The higher energy shape resonance is apparently masked by the presence of the dominant nonresonant επ channel. In addition to information on the photoionization dynamics, these results also provide spectroscopic data on the ionic potential surfaces. Specifically, we obtain ratios of Franck–Condon factors for N2O+ (A→X) transitions which are useful for testing calculated properties of the ion.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 89 (1988), S. 4048-4053 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We investigate the dynamics of molecular core–hole decay using dispersed fluorescence from an ionic valence–hole state in N2. A core–hole excited state is created via the N2(1s→1 π*g) transition, and this state electronically autoionizes to the N+2(B 2Σ+u) state. The vibrational branching ratios for the N+2(B 2Σ+u) state are then determined from N+2(B 2Σ+u→X 2Σ+g) fluorescence. Fundamental aspects of core–hole state decay emerge clearly from these measurements. In particular, interference effects due to lifetime broadening of vibrational levels of the core–hole state can be investigated quantitatively using this method. As a result, dispersed fluorescence detection serves as a powerful tool for investigating R-dependent aspects of molecular core–hole resonances. The experimental results do not agree with predictions based on previous theoretical developments, and possible causes for the discrepancy are discussed.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1520-510X
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Aquaculture research 26 (1995), S. 0 
    ISSN: 1365-2109
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Cage farming of salmonids in floating cage systems has become widespread in the Scottish Highlands over the past 15 years. Determination of wastewater discharges and composition from such facilities, unlike land-based ones, has had to rely exclusively upon results of published studies of waste outputs. To limit impacts of such activities, regulatory authorities have used such data together with lake nutrient mass-balance models to assess likely increase in phosphorus (P) due to both organic and inorganic loading of cage farm losses. Results of biannual surveys between 1988 and 1991 of P levels in six lochs used for cage farming in Scotland, together with estimates of nutrient input on the basis of feeding and fish biomass data, are presented. Results demonstrate that in small basins, where cage farms are the only substantial source of P. model predictions of rises in P level reflect actual changes in water quality. However, in larger, more complex basins, where cage farms represent one of a number of sources of P, and the mass of P present in the nutrient cycle is far greater, use of such models is found to be inappropriate to assess the impact of such operations. Clear effects on loch nutrient levels are observed in the immediate vicinity of the cages. It is concluded that whilst such mass-balance models may estimate total contributions from cage farms accurately, use of such models to determine annual nutrient dynamics of complex sites requires more robust sampling programmes than have at present been implemented.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Aquaculture research 29 (1998), S. 0 
    ISSN: 1365-2109
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Although the waste dispersion models used in salmonid marine cage aquaculture could potentially be applied in freshwater cage aquaculture, much of relevant data on the waste particle parameters are unavailable. The present study provides new data on the wet densities of diets, the fall velocities of diets, the fall velocities of faecal matter and waste particle size. A significant increase of densities caused by the immersion time in water was observed. The wet density obtained from 60-s immersion time was found to be the effective settling density of diets. Fall velocities of salmonid diets were non-Stokesian and ranged from 0.02 to 0.12 ms−1. These fall velocities did not significantly vary with water temperature. Fractionation of collected solid wastes from experimental tanks revealed that almost 60s% by mass was retained on 2000-, 1000- and 500-μm meshes. The fall velocities of these fractions were found to vary between 0.015 and 0.030ms−1, The waste fraction that passed through a 500-μm mesh had an estimated median diameter of 114.4 Jim. The observed fall velocities of both diets and solid wastes were lower than those commonly used in modelling waste dispersion in the marine environment. However, because of the relatively slow current velocities in most freshwater environments, it is expected that the wastes will tend to accumulate locally at cages.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of applied ichthyology 10 (1994), S. 0 
    ISSN: 1439-0426
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Waste production from fish farm sites presents a number of problems for regulatory authorities; sites are often distant from laboratories, whilst waste output fluctuates rapidly during the day in response to both the activity of the fish and production methods employed at any site (i.e. feeding regime, tank cleaning). Two land-based sites in NW Scotland, producing Atlantic salmon (Salmo salar) juveniles were visited regularly over a 4-month period, and outputs measured on a diurnal cycle to determine the most appropriate strategy for sampling such waste discharges. The BOD5 of discrete samples taken at hourly intervals and a single composite sample for the whole 24-h period were compared for the pre- and post-treatment outflow sites for BOD5 content. The BOD5 value of the untreated composite sample was shown to exceed that of the mean of all 24 1-h discrete samples in a highly significant manner. It is suggested that the presence of solid particles has a disproportionate effect on BOD5 value of composite samples.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Water Resources Association 32 (1996), S. 0 
    ISSN: 1752-1688
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Architecture, Civil Engineering, Surveying , Geography
    Notes: : Recent studies suggest that waste generation from the freshwater phase of Atlantic salmon (Salmo salar L.) production varies considerably on an annual basis. A fish farm on the West Coast of Scotland was visited regularly during a two-year period to determine inflow and outflow water quality. Waste output budgets of suspended solids (SS), biochemical oxygen demand (BOD), total nitrogen (TN), total phosphorus (TP), total ammonia nitrogen (TAN = NH3+NH4+), dissolved reactive phosphorus (DRP) and total phosphorus (TP) were produced. The annual waste loadings obtained were 71 kg TN t fish−1 yr−1 (one year of data only), 10.9–11.1 kg TP t fish−1 yr−1, 1.2–2.1 kg DRP t fish−1 yr−1, 422–485 kg BOD5 t fish−1 yr−1, 327–337 kg SS t fish−1 yr−1, and 30–35 kg TAN-N t fish−1 yr−1. Simple linear regression models relating waste parameter production to water temperature and feeding regime were developed. When compared to existing data for other salmonid production systems, greater ranges of daily waste loadings were observed. Wide variations in concentrations of these parameters during a daily cycle were also observed, suggesting that mass balance estimates of waste production will provide more robust estimates of waste output than frequent monitoring of outflow water quality.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Bulletin of environmental contamination and toxicology 63 (1999), S. 691-697 
    ISSN: 1432-0800
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Medicine
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 86 (1996), S. 235-249 
    ISSN: 1573-2932
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Studies of waste generation from the freshwater phase of Atlantic salmon (Salmo salar L.) production have not been substantially updated since the mid 1980's, and advances in husbandry prectices designed to reduce wastage which have taken place in that period therefore remain unconsidered. In order to determine if reductions have been achieved, two Scottish fish farms were visited on a number of occasions during one year, and outputs of suspended solids (SS), biochemical oxygen demand (BOD), total ammonia nitrogen (TAN) (NH3+NH4 +), dissolved reactive and total phosphorus (DRP, TP) were monitored. The range of waste loadings obtained were 9.1–10.0 kg TP t fish−2 yr−1, 410 kg BOD5 t fish−1 yr−1, 191–606 kg SS t fish−1 y−1, and 20.3–39.3 kg TAN-N t fish−1 yr−1. Compared to existing data, a greater range of daily waste loadings were observed, suggesting that more frequent monitoring is required to reduce variations observed in the data set, and to obtain accurate information on waste outputs from such operations. Modifications of feeding methods remains a route through which further reductions in waste outputs may be made.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Quantitative microbiology 2 (2000), S. 171-188 
    ISSN: 1572-9923
    Keywords: Listeria monocytogenes ; big-bale silage ; mathematical modelling ; computer simulation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract A computer simulation model which describes the spatial and temporal variation in the extent of listerial contamination within a damaged silage bale is presented. The silage bale is assumed to be split into a number of distinct sites and these sites are represented by a two dimensional lattice structure. Each site is classified in relation to its listerial composition. This classification results in three states which are dormant, active and unpopulated. Sites change state as a result of the movement of oxygen through the bale. This movement is initiated when a hole is punched in the plastic covering of the bale. The model is stochastic in nature and at any time following damage, the proportion of the bale which is contaminated is calculated. Furthermore, the spatial distribution of contaminated sites is predicted. The models are a first attempt at introducing structure into the selection process for feeding silage. We highlight areas of future research which will be invaluable for validation and practical use of the model.
    Type of Medium: Electronic Resource
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